FIGURE S34 Profile of the calculated relative ΔG for the reaction of hydrogen peroxide and complex 2, the formation of hydroperoxo species and by removal of ‐•OH radical stabilization of FeIV=O intermediate. Yan Zhang, Xinjiang Cui, Feng Shi, and Youquan Deng . Facile construction of leaf-like WO Liquid-phase oxidation of benzyl alcohol to benzaldehyde by tertiary butyl hydroperoxide (at 95 °C) over nanogold supported on TiO2 and other transition-metal oxides (viz, MnO2, Fe2O3, CoOx, NiO, CuO, ZnO, and ZrO2) or rare-earth oxides (viz, La2O3, Sm2O3, Eu2O3, and Yb2O3) by the homogeneous deposition−precipitation (HDP) method has been investigated. Effective dispersion of Au and Au–M (M=Co, Ni, Cu and Zn) bimetallic nanoparticles over TiO2 grafted SBA-15: Their catalytic activity on dehydroisomerization of α-pinene. Hang Cong, Zhao-Jie Li, Yong-Huan Wang, Zhu Tao, Takehiko Yamato, Sai-Feng Xue, Gang Wei. Highly efficient nanosized Mn and Fe codoped ceria-based solid solutions for elemental mercury removal at low flue gas temperatures. FIGURE S1 1H NMR spectra of ligand L1 in DMSO‐d6, FIGURE S2 1H NMR spectra of ligand L1 with D2Oin DMSO‐d6, FIGURE S4 UV–visible spectrum of ligand L1, FIGURE S5 1H NMR spectra of ligand L2 in DMSO‐d6, FIGURE S6 1H NMR spectra of ligand L2 with D2Oin DMSO‐d6, FIGURE S8 UV–visible spectrum of ligand L2, FIGURE S9 IR spectrum of complex [FeII(L1)2](ClO4)2, FIGURE S10 ESI‐MS spectrum of complex [FeII(L1)2]2+(1), FIGURE S11 UV–visible spectrum of complex[FeII(L1)2](ClO4)2, FIGURE S12 1H NMR spectrum of complex [FeII(L1)2](ClO4)2, FIGURE S13 IR spectrum of complex [FeII(L2)2](PF6)2, FIGURE S14 UV–visible spectrum of complex[FeII(L2)2](PF6)2, FIGURE S15 1H NMR spectrum of complex [FeII(L2)2](PF6)2, FIGURE S16 ESI‐MS spectrum of complex [FeII(L2)2]2+(2). Making Full Use of the Oxidizing Equivalents in Bromate in the Selective Oxidation of Thiols, Sulfides, and Benzylic/Secondary Alcohols into Disulfides, Sulfoxides, and Aldehydes/Ketones. Evaluation of catalytic activity of MeOx/sepiolite in benzyl alcohol oxidation. Background . You have to login with your ACS ID befor you can login with your Mendeley account. A. Corma, A. Leyva-Pérez, and Maria J. Sabater . SMA/Py/ZnO as a new biocompatible polymer supported nanocatalyst for the synthesis of chromeno[2,3- The novel green reaction was catalyzed by nano Au/γ-Al2O3. The relative Gibbs free energies are given in kcal mol−1, FIGURE S39 GC–MS spectra (m/z) of degraded products of orange II dye, FIGURE S40 GC–MS spectra (m/z) of degraded products of orange II dye, FIGURE S41 GC–MS spectra (m/z) of degraded products of orange II dye, FIGURE S42 GC–MS spectra (m/z) of degraded products of orange II dye, FIGURE S43 GC–MS spectra (m/z) of degraded products of methylene blue dye, FIGURE S44 GC–MS spectra (m/z) of degraded products of methylene blue dye, FIGURE S45 GC–MS spectra (m/z) of degraded products of methylene blue dye. Review of supported metal nanoparticles: synthesis methodologies, advantages and application as catalysts. RuO 2 supported NaY zeolite catalysts: Effect of preparation methods on catalytic performance during aerobic oxidation of benzyl alcohol. Journal of Molecular Catalysis A: Chemical. 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DFT and TD−DFT calculations revealed that the oxidation reactions were performed through high‐valent iron center and a probable reaction mechanism was proposed. nanoflakes decorated on g-C Working off-campus? Matumuene Joe Ndolomingo, Reinout Meijboom. Supported Gold Nanoparticles as Catalysts for the Oxidation of Alcohols and Alkanes. d of H2O2 in MeCN at −0 °C. Journal of Science: Advanced Materials and Devices. Huan-Tsung Chang, Zih-Yu Shih, Arun Prakash Periasamy, Guan-Lin Lin. Active and Stable Platinum/Ionic Liquid/Carbon Nanotube Electrocatalysts for Oxidation of Methanol. containing the substrate (benzyl alcohol) and the product, (benzaldehyde) and the aqueous phase with the oxidant, hydrogen peroxide, and the catalyst (Scheme 1). Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 2 Assal, Mujeeb Khan, Abdulrahman Alwarthan, M. Rafiq H. Siddiqui. Mulisa Nemanashi-Maumela, Isaac Nongwe, Reagile Clifford Motene, Bianca Leigh Davids, Reinout Meijboom. 2 C Scheme 1-Schematiziation of oxidation of benzyl alcohol to benzaldehyde using a membrane at the interface of aqueous phase and organic phases, containing respectively 3 These iron complexes have been characterized using ESI−MS analysis and molecular structures were determined by X‐ray crystallography. Any queries (other than missing content) should be directed to the corresponding author for the article. The present study focuses on the smooth oxidation of benzyl alcohol by air in a vapor phase process affording benzaldehyde with high selectivity and yield, using mono- and bimetallic gold–copper on silica catalyst. Dual Stimuli-Responsive Copper Nanoparticles Decorated SBA-15: A Highly Efficient Catalyst for the Oxidation of Alcohols in Water. Supported Gold Nanoparticles as Reusable Catalysts for Oxidation Reactions of Industrial Significance. In Situ Growth Route To Fabricate Ternary Co–Ni–Al Mixed-Metal Oxide Film as a Promising Structured Catalyst for the Oxidation of Benzyl Alcohol. These complexes were also utilized for the degradation of orange II and methylene blue dyes. Ai Nozaki, Yasutomo Tanihara, Yasutaka Kuwahara, Tetsutaro Ohmichi, Kohsuke Mori, Takeshi Nagase, Hiroyuki Y. Yasuda, Christophe Calers, Catherine Louis, Hiromi Yamashita. The gold deposition method strongly influenced the amount of gold that was deposited on TiO2, the gold particle size distribution, and also the surface Au3+/Au0 ratio; using the HDP method, the gold deposition was much larger, the gold particle size was smaller, the gold particle size distribution was much narrower, and the Au3+/Au0 ratio was higher. Modified graphene supported Ag–Cu NPs with enhanced bimetallic synergistic effect in oxidation and Chan–Lam coupling reactions. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. ESI − MS analysis also helped to understand the generation of intermediate species like FeIII−OOH and FeIV=O. Find more information about Crossref citation counts. Journal of Industrial and Engineering Chemistry. Copyright © 2020 Elsevier B.V. or its licensors or contributors. Guowu Zhan, Yingling Hong, Fenfen Lu, Abdul-Rauf Ibrahim, Mingming Du, Daohua Sun, Jiale Huang, Qingbiao Li, Jun Li. Free solvent oxidation of molecular benzyl alcohol by newly synthesized AuPd/titania catalysts. Please reconnect. FIGURE S27 Packing diagram for the complex 1, showing the short interaction between molecule and the counter ions, FIGURE S28 Packing diagram for the complex 2, showing the short interaction between molecule and the counter ions, SCHEME S2 Degraded product of methylene blue dye, FIGURE S29 Degradation of methylene blue (1x10−3M) in the presence of complex [FeII(L1)2](ClO4)2 (a) and [FeII(L2)2](PF6)2 (b) (1x10−6M) with H2O2 (20 equivalent) in CH3CN, FIGURE S30 Reaction of complex 1 (1x10−6M) with DPPH (1x10−5M) in the presence of H2O2 (20 μM), FIGURE S31 Reaction of complex 2 (2x10−6M) with DPPH (2x10−5M) in the presence of H2O2 (20 μM), FIGURE S32 Geometry optimizations, of intermediates FeIII‐OOH and FeIV=O species. Norasidah Mohd JamJam, Yun Hin Taufiq Yap, Ernee Noryana Muhamad, Mohd Izham Saiman, Tawfik A. Saleh. Au and Ag nanoparticles encapsulated within silica nanospheres using dendrimers as dual templating agent and their catalytic activity. 2 Find more information on the Altmetric Attention Score and how the score is calculated. Use the link below to share a full-text version of this article with your friends and colleagues. Luísa Margarida Dias Ribeiro de Sousa Martins, Sónia Alexandra Correia Carabineiro, Jiawei Wang, Bruno Gonçalo Martins Rocha, Francisco José Maldonado-Hódar, Armando José Latourrette de Oliveira Pombeiro. 3 Expired - Lifetime Application number 3 You’ve supercharged your research process with ACS and Mendeley! Ashish Kumar, Vanama Pavan Kumar, Amirineni Srikanth, Venkataraman Vishwanathan, Komandur V. R. Chary. Ashish Kumar, Vanama Pavan Kumar, Venkataraman Vishwanathan, Komandur V.R. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Yangming Lin, Kuang-Hsu Tim Wu, Linhui Yu, Saskia Heumann, Dang Sheng Su. Synthesis of polymeric ionic liquid microsphere/Pt nanoparticle hybrids for electrocatalytic oxidation of methanol and catalytic oxidation of benzyl alcohol. Jianhu Yang, Lihua Qiu, Baoqiang Liu, Yingjing Peng, Feng Yan, Songmin Shang.